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| INTRODUCTION
TO POLYUREA |
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The coatings industry has come a long
way from brushes and buckets. Over the past 30 years, chemical engineers have
formulated innovative polymer resins that have a range of modulus (from high
to low), better fire retardancy, low VOCs and faster reaction times. Today's
modern coatings, including polyurethane and polyurea, are among the most advanced
resins developed. These polyureas, more than any other polymer coating, stand
out in their versatility, strength and longevity. They are the next step in
the coatings evolution. At the same time, advances
in coatings technology have also led to the development of spray, injection
and rotationally-cast application equipment that also improves the performance of polyureas.
In particular, plural component equipment technology has been improved to
make spray application easier, more uniform in coverage, applicable at lower
pressures (as low as 1,000 psi) and generating less over spray or fogging.
Polyurea materials have
two components: the isocyanates quasi-prepolymer and a resin blend. The resin
blend is a combination of amine-terminated chain extenders. Unlike polyurethanes,
no polyols are used in the manufacture of polyurea resins. When the materials
are mixed together in the application equipment, the isocyanates and the amine
resins react to form a urea linkage. Introduced in 1989 by
the Texaco Chemical Co., polyurea was regarded by many in the coatings industry
as an "over-hyped" product with exaggerated features and benefits.
True, polyurea systems and technology have many outstanding properties. However,
many manufacturers of traditional coating material discounted the claims of
polyurea being the "wonder" product; as a result, many manufacturers
and end users lost sight of the true advantages of the product. Many old-guard coatings
manufacturers did not differentiate between polyurethane and polyurea. All
coatings, whether polyether amines (polyurea component) or polyester/polyether
hydroxyl (polyurethane urethane component) resins, were identified as polyurethanes.
Only in the past seven years have many companies differentiated these coatings.
OEM manufacturers, contractors, engineers and fabricators needed
a fast-cure, moisture-insensitive coating system. They required a variety
of physical properties, excellent adhesion, smooth surface flow out, superior
tensile strength and high abrasion resistance. A polyurea system fit that
description. The main physical properties of polyurea explain their success. |
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